KMID : 1059519940380040319
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Journal of the Korean Chemical Society 1994 Volume.38 No. 4 p.319 ~ p.327
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Syntheses and Properties of Polydentate Schiff Base and Their Cu(¥±) Complexes
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Kim Sun-Deuk
Shin Yun-Yeol Jang Ki-Ho
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Abstract
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The novel Schiff base hexadentate ligand, bis-(salicylaldehyde)-triethylentetramine (BSTT) and heptadentate ligand, bis-(salicylaldehyde)-tetraethylenpentamine(BSTP) were synthesized by the reaction of salicylaldehydes with triethylenetetramine and tetraethylenepentamine, having four and five nitrogen atoms, respectively. These liquid Schiff base ligands were become in form of the pale-yellow crystals in the specific pH 4.0 by adding acetic acid concentrated hydrochloric acid. The Cu(¥±) complexes of the Schiff bases were synthesized by reaction of the Schiff base with Cu(¥±) ion and their possible structures were proposed by several analytical data, and physical and chemical properties.
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